coolant level MERCEDES-BENZ S-Class SEDAN 2016 W222 Owner's Manual

Removing...................................... .185
Storing ...........................................1 83
Warming up ................................... 182
Charging the high-voltage battery
(important safety notes) ................... 180
Chauffeur mode
Display message ............................ 310
Fully reclined position .................... 114
General notes ................................ 111
Installing the head restraint ........... 113
Moving front-passenger seat into
the chauffeur position .................... 112
Moving the front-passenger seat
into the normal position ................. 113
Removing the head restraint .......... 113
Child
Restraint system .............................. 62
Child seat
Forward-facing restraint system ...... 66
LATCH-type (ISOFIX) child seat
anchors ............................................ 63
On the front-passenger seat ............ 65
Rearward-facing restraint system .... 66
Top Tether ....................................... 64
Child-proof locks
Important safety notes .................... 66
Rear doors ....................................... 67
Children
Special seat belt retractor ............... 62
Cigarette lighter ................................ 335
Cleaning
Mirror turn signal ........................... 362
Climate control
Automatic climate control ............. 141
Controlling automatically ............... 147
Cooling with air dehumidification .. 146
Defrosting the windows ................. 151
Defrosting the windshield .............. 151
ECO start/stop function ................ 145
General notes ................................ 140
Immediate pre-entry climate con-
trol ................................................. 158
Indicator lamp ................................ 147
Ionization ....................................... 155
Notes on using the automatic cli-
mate control .................................. 145
Overview of systems ...................... 140
Perfume atomizer .......................... 153 Pre-entry climate control at
departure time ............................... 157
Pre-entry climate control via
key ... 155
P

roblem with the rear window
defroster ........................................ 152
Problems with cooling with air
dehumidification ............................ 147
Rear control panel ......................... 141
Refrigerant ..................................... 432
Refrigerant filling capacity ............. 432
Setting the air distribution ............. 149
Setting the air vents ...................... 158
Setting the airflow ......................... 150
Setting the climate mode ............... 148
Setting the temperature ................ 148
Switching air-recirculation mode
on/off ............................................ 152
Switching on/off ........................... 145
Switching residual heat on/off ...... 152
Switching the rear window
defroster on/off ............................ 151
Switching the synchronization
function on and off ........................ 150
Climate control system
Climate control .............................. 145
Cockpit
Overview .......................................... 32
COLLISION PREVENTION ASSIST
PLUS
Activating/deactivating ................. 270
Display message ............................ 284
Operation/notes .............................. 71
COMAND display
Cleaning ......................................... 364
Combination switch .......................... 131
Consumption statistics (on-board
computer) .......................................... 262
Convenience closing feature .............. 96
Convenience opening feature ............ 95
Coolant (engine)
Checking the level ......................... 356
Display message ............................ 294
Displaying the temperature (on-
board computer) ............................ 269
Filling capacity ............................... 431
Important safety notes .................. 431
Temperature gauge ........................ 257
Warning lamp ................................. 320
6Index

V
Vanity mirror (in the sun visor)........ 333
Vehicle
Correct use ...................................... 29
Data acquisition ............................... 29
Display message ............................ 308
Equipment ....................................... 25
Individual settings .......................... 269
Limited Warranty ............................. 29
Loading .......................................... 394
Locking (in an emergency) ............... 88
Locking (SmartKey) .......................... 79
Lowering ........................................ 409
Maintenance .................................... 26
Operating safety .............................. 27
Parking .......................................... 189
Parking for a long period ................ 192
Pulling away ................................... 165
Raising ........................................... 406
Reporting problems ......................... 29
Securing from rolling away ............ 406
Towing away .................................. 379
Transporting .................................. 381
Unlocking (in an emergency) ........... 87
Unlocking (SmartKey) ...................... 79
Vehicle data ................................... 433
Vehicle dimensions ........................... 433
Vehicle emergency locking ................ 88
Vehicle identification number
see VIN
Vehicle identification plate .............. 426
Vehicle level
Active Body Control ABC ............... 210
AIRMATIC ...................................... 212
Display message ............................ 300
Vehicle tool kit .................................. 367
Video
Operating the DVD ......................... 267
VIN
Type plate ...................................... 426
W
WarningStickers ........................................... 42
Warning and indicator lamps
ABS ................................................ 316 Brakes ........................................... 315
Check Engine ................................. 320
Coolant .......................................... 320
Distance warning ........................... 322
ESP
®.............................................. 317
ESP®OFF ....................................... 319
Fuel tank ........................................ 320
General notes ................................ 313
Hybrid drive system ....................... 315
Overview .......................................... 34
Parking brake ................................ 319
PASSENGER AIR BAG ...................... 46
RBS (Recuperative Brake Sys-
tem) ............................................... 315
Reserve fuel ................................... 320
Restraint system ............................ 319
Seat belt ........................................ 313
Steering ......................................... 324
Tire pressure monitor .................... 323
Warranty .............................................. 25
Washer fluid
Display message ............................ 311
Wheel and tire combinations
Tires ............................................... 412
Wheel bolt tightening torque ........... 409
Wheel chock ...................................... 406
Wheels
Changing a wheel .......................... 405
Checking ........................................ 385
Cleaning ......................................... 361
General notes ................................ 410
Important safety notes .................. 384
Information on driving .................... 384
Interchanging/changing ................ 405
Mounting a new wheel ................... 409
Mounting a wheel .......................... 406
Removing a wheel .......................... 408
Snow chains .................................. 386
Storing ........................................... 405
Tightening torque ........................... 409
Wheel size/tire size ....................... 410
Window curtain air bag
Display message ............................ 288
Operation ......................................... 53
Windows
see Side windows
22Index

Useful information
i
This Operator's Manual describes all models
and all standard and optional equipment of
your vehicle available at the time of publica-
tion of the Operator's Manual. Country-spe-
cific differences are possible. Please note
that your vehicle may not be equipped with all
features described. This also applies to
safety-related systems and functions.
iRead the information on qualified specialist
workshops (Ypage 28).
Hybrid vehicles
General notes
Hybrid technology combines a fuel efficient
internal combustion engine with a powerful
electric motor.
Important safety notes
Danger of electric shock
GDANGER
The vehicle's high-voltage electrical system is under high voltage. If you modify components
in the vehicle's high-voltage electrical system
or touch damaged components, you may be
electrocuted. The components in the vehi-
cle's high-voltage electrical system may be
damaged in an accident, although the damage
is not visible. There is a risk of fatal injury.
Following an accident, do not touch any high-
voltage components and never modify the
vehicle's high-voltage electrical system. Have
the vehicle towed away after an accident and
the vehicle's high-voltage electrical system
checked by a qualified specialist workshop.
When towing a vehicle after an accident, be sure
to observe the following sections:
RTransporting the vehicle (Ypage 381)
RTowing a vehicle with both axles on the
ground (Ypage 380)
Read the safety instructions on towing and tow-
starting (
Ypage 379).
All components of the hybrid drive system are
marked with yellow warning stickers that warn
you of the danger of high voltage. The cables of
the vehicle's high-voltage electrical system are
orange in color.
The ignition must be switched off when carrying
out general tasks, such as adding washer fluid to
the windshield washer system or checking the
coolant level.
Automatic switching off of the hybrid
drive system
If components of the restraint system are acti-
vated during an accident, the hybrid drive sys-
tem is automatically deactivated.
The hybrid drive system is not activated when
the vehicle is started if:
Ran electrical short circuit is detected in the
hybrid drive system
Ran electrical connection in the hybrid drive
system is disconnected
This ensures that you do not come into contact
with high voltage.
Manual switching off of the hybrid drive
system
The hybrid drive system can be deactivated
manually using the high voltage switch-off
device.
!To prevent damage to the hybrid drive sys-
tem please observe the following instruc-
tions:
Ronly deactivate the hybrid drive system
manually in the following situations.
Rwork on the hybrid drive system may only
be carried out at a qualified specialist work-
shop, even when it has been deactivated
manually.
42Hybrid vehicles
Safety

Problems with the engine
ProblemPossible causes/consequences andMSolutions
The engine does not
start. The starter motor
can be heard.RThere is a malfunction in the engine electronics.
RThere is a malfunction in the fuel supply.
Before attempting to start the engine again:
XTurn the SmartKey back to position 0in the ignition lock.
or
XPress the Start/Stop button repeatedly until all indicator lamps in
the instrument cluster go out.
XTry to start the engine again (Ypage 164). Avoid excessively long
and frequent attempts to start the engine as these will drain the
battery.
If the engine does not start after several attempts:
XConsult a qualified specialist workshop.
The engine does not
start. You cannot hear
the starter motor.The on-board voltage is too low because the battery is too weak or
discharged.
XJump-start the vehicle (Ypage 376).
If the engine does not start despite attempts to jump-start it:
XConsult a qualified specialist workshop.
The starter motor was exposed to a thermal load that was too high.
XTry to start the engine again.
If the engine still does not start:
XConsult a qualified specialist workshop.
The engine is not running
smoothly and is misfir-
ing.There is a malfunction in the engine electronics or in a mechanical
component of the engine management system.
XOnly depress the accelerator pedal slightly.
Otherwise, non-combusted fuel may get into the catalytic converter
and damage it.
XHave the cause rectified immediately at a qualified specialist work-
shop.
The coolant temperature
gauge shows a value
above 248 ‡ (120 †).The coolant level is too low. The coolant is too hot and the engine is no
longer being cooled sufficiently.
XStop as soon as possible and allow the engine and the coolant to
cool down.
XCheck the coolant level (Ypage 356). Observe the warning notes
as you do so and add coolant if necessary.
Driving169
Driving and parking
Z

Outside temperature display
You should pay special attention to road condi-
tions when temperatures are around freezing
point.
Bear in mind that the outside temperature dis-
play indicates the temperature measured and
does not record the road temperature.
The outside temperature display is in the multi-function display (
Ypage 258).
There is a short delay before a change in outside
temperature is shown in the multifunction dis-
play.
Coolant temperature display
GWARNING
Opening the hood when the engine is over-
heated or when there is a fire in the engine
compartment could expose you to hot gases
or other service products. There is a risk of
injury.
Let an overheated engine cool down before
opening the hood. If there is a fire in the
engine compartment, keep the hood closed
and contact the fire department.
!A display message is shown if the coolant
temperature is too high.
If the coolant temperature is above 257 ‡
(125 †) do not drive any further. The engine
will otherwise be damaged.
All vehicles except PLUG‑ IN HYBRID vehicles:
the coolant temperature gauge is in the lower
area of the tachometer (
Ypage 33).
PLUG-IN HYBRID vehicles: the multifunction dis-
play shows the coolant temperature in the
Coolant
submenu (Ypage 269).
Under normal operating conditions and with the
specified coolant level, the coolant temperature
may rise to 255 ‡ (124 †).
Operating the on-board computer
:Multifunction display
;Right control panel
=Left control panel
XTo activate the on-board computer: turn
the SmartKey to position 1in the ignition lock.
You can control the multifunction display and
the settings in the on-board computer using the
buttons on the multifunction steering wheel.
Left control panel
òROpens the menu list
9
:Press briefly:
RScrolls in lists
RSelects a menu or function
RIn the RadioorMediamenu:
opens the track or station list and
selects a station, an audio track or
a video scene
RIn the Telephonemenu: switches
to the phone book and selects a
name or a telephone number
9
:Press and hold:
RScrolls quickly through all lists
RIn the RadioorMediamenu:
selects a station, audio track or
video scene using rapid scrolling
RIn the Telephonemenu: starts
rapid scrolling if the phone book is
open
Displays and operation257
On-board computer and displays
Z

RDistance warning and the autonomous
braking function COLLISION PREVENTION
ASSIST PLUS (
Ypage 71)
RPRE-SAFE®Brake (Ypage 75)
RActive Blind Spot Assist (Ypage 234)
RATTENTION ASSIST (Ypage 228)
RActive Lane Keeping Assist (Ypage 237)
XPress:to display the ATTENTION ASSIST
assessment.
Service menu
Introduction
Depending on the equipment installed in the
vehicle, you have the following options in the
Service
menu:
RCalling up display messages in message
memory (Ypage 277)
RRestarting the tire pressure loss warning sys-
tem (Ypage 394)
RChecking the tire pressure electronically
(Ypage 390)
RCalling up the service due date (Ypage 358).
RDisplaying the coolant temperature (PLUG-IN
HYBRID vehicles) (Ypage 269)
RChecking the oil level using the on-board com-
puter (Ypage 355) (only S 600, Mercedes-
Maybach S 600 and Mercedes-AMG S 65
models)
Displaying the coolant temperature
The Coolantmenu is only available on PLUG ‑IN
HYBRID vehicles.
XPress the òbutton on the steering wheel
to open the menu list.
XPress :or9 on the steering wheel to
select the Servicemenu.
XConfirm by pressing aon the steering
wheel.
XPress the :or9 button to select
Coolant.
XPress ato confirm the selection.
The multifunction display shows the coolant
temperature in a bar display.
Settings menu
Introduction
Depending on the equipment installed in the
vehicle, you have the following options in the
Settings
menu:
RChanging assistance settings (Ypage 269)
RChanging HYBRID settings (PLUG-IN HYBRID
vehicles) (Ypage 272)
RChanging head-up display settings
(Ypage 273)
RChanging the light settings (Ypage 274)
RChanging the instrument cluster settings
(Ypage 274)
RRestoring the factory settings (Ypage 275)
Assistance submenu
Deactivating/activating ESP®
Observe the "Important safety notes" section in
the description of ESP®(Ypage 73).
Menus and submenus269
On-board computer and displays
Z

Engine
Display messagesPossible causes/consequences andMSolutions
+
CheckCoolantLevelSee Operator's Man‐ual
The coolant level is too low.
!Avoid making long journeys with too little coolant in the engine
cooling system. The engine will otherwise be damaged.
XAdd coolant, observing the warning notes before doing so
(Ypage 356).
If you have to add coolant frequently:
XContact a qualified specialist workshop and have the engine cooling
system checked.
?The fan motor is faulty.
XAt coolant temperatures below 257 ‡(125 †), drive to the nearest
qualified specialist workshop.
XAvoid heavy loads on the engine as you do so, e.g. driving in moun-
tainous terrain and stop-start traffic.
?
Coolant Too HotStop Vehicle TurnEngine Off
The coolant is too hot.
A warning tone also sounds.
GWARNING
Do not drive when your engine is overheated. This can cause some
fluids which may have leaked into the engine compartment to catch
fire.
Steam from the overheated engine can also cause serious burns which
can occur just by opening the hood.
There is a risk of injury.
XPull over and stop the vehicle safely and switch off the engine, pay- ing attention to road and traffic conditions.
XSecure the vehicle against rolling away (Ypage 189).
XWait until the engine has cooled down.
XMake sure that the air supply to the engine radiator is not blocked,e.g. by snow, slush or ice.
XDo not start the engine again until the display message goes out and
the coolant temperature is below 257 ‡ (125 †). Otherwise, the
engine could be damaged.
XPay attention to the coolant temperature display.
If the temperature increases again:
XVisit a qualified specialist workshop immediately.
Under normal operating conditions and with the specified coolant
level, the coolant temperature may rise to 255 ‡ (124 †).
294Display messages
On-board computer and displays

Engine
Warning/
indicator
lampNSignal type
Possible causes/consequences and M
Solutions
;NThe yellow Check Engine warning lamp lights up while the engine is running.
There may be a malfunction, for example:
Rin the engine management
Rin the fuel injection system
Rin the exhaust system
Rin the ignition system
Rin the fuel system
The emission limit values may be exceeded and the engine may be in emergency
mode.
XVisit a qualified specialist workshop immediately.
iIn some states, you must immediately visit a qualified specialist workshop as
soon as the yellow Check Engine warning lamp lights up. This is due to the legal
requirements in effect in these states. If in doubt, check whether such legal
regulations apply in the state in which you are currently driving.
8N The yellow reserve fuel warning lamp lights up while the engine is running.
The fuel level has dropped into the reserve range.
XRefuel at the nearest gas station.
8N The yellow reserve fuel warning lamp flashes while the vehicle is in motion.
In addition, the ;Check Engine warning lamp may light up.
The fuel filler cap is not closed correctly or the fuel system is leaking.
XCheck that the fuel filler cap is correctly closed.
XIf the fuel filler cap is not correctly closed: close the fuel filler cap.
XIf the fuel filler cap is closed:visit a qualified specialist workshop.
?NThe red coolant warning lamp comes on while the engine is running. The coolant
temperature gauge is at the beginning of the cold range.
The temperature sensor for the coolant temperature gage is defective.
The coolant temperature is no longer being monitored. There is a risk of engine
damage if the coolant temperature is too high.
XPull over and stop the vehicle safely and switch off the engine, paying attention
to road and traffic conditions. Do not continue driving under any circumstances.
XSecure the vehicle against rolling away (Ypage 189).
XConsult a qualified specialist workshop.
320Warning and indicator lamps in the instrument cluster
On-board computer and displays

Warning/
indicator
lampNSignal type
Possible causes/consequences and M
Solutions
?NThe red coolant warning lamp comes on while the engine is running.
The coolant level is too low.
If the coolant level is correct, the airflow to the engine radiator may be blocked or
the electric engine radiator fan may be malfunctioning.
The coolant is too hot and the engine is no longer being cooled sufficiently.
XObserve the additional display messages in the multifunction display.
XPull over and stop the vehicle safely and switch off the engine, paying attention
to road and traffic conditions.
XSecure the vehicle against rolling away (Ypage 189).
XLeave the vehicle and keep a safe distance from the vehicle until the engine has cooled down.
XCheck the coolant level and add coolant, observing the warning notes
(Ypage 356).
XIf you have to add coolant frequently, have the engine cooling system checked.
XMake sure that the air supply to the engine radiator is not blocked, e.g. by snow,
slush or ice.
XDo not start the engine again until the coolant temperature is below 257 ‡
(125 †). Otherwise, the engine could be damaged.
XDrive to the nearest qualified specialist workshop.
XAvoid heavy loads on the engine as you do so, e.g. driving in mountainous terrain
and stop-start traffic.
?N The red coolant warning lamp comes on while the engine is running. A warning
tone also sounds.
The coolant temperature has exceeded 255 ‡(124 †). The airflow to the engine
radiator may be blocked or the coolant level may be too low.
GWARNING
The engine is not being cooled sufficiently and may be damaged.
Do not drive when your engine is overheated. This can cause some fluids which
may have leaked into the engine compartment to catch fire.
Steam from the overheated engine can also cause serious burns which can occur
just by opening the hood.
There is a risk of injury.
XObserve the additional display messages in the multifunction display.
XPull over and stop the vehicle safely and switch off the engine, paying attention
to road and traffic conditions.
XSecure the vehicle against rolling away (Ypage 189).
XLeave the vehicle and keep a safe distance from the vehicle until the engine has
cooled down.
XCheck the coolant level and add coolant, observing the warning notes
(Ypage 356).
XIf you have to add coolant frequently, have the engine cooling system checked.
XMake sure that the air supply to the engine radiator is not blocked, e.g. by snow,
slush or ice.
Warning and indicator lamps in the instrument cluster321
On-board computer and displays
Z

GWARNING
If engine oil comes into contact with hot com- ponents in the engine compartment, it may
ignite. There is a risk of fire and injury.
Make sure that engine oil is not spilled next to
the filler neck. Let the engine cool down and
thoroughly clean the engine oil off the com-
ponents before starting the engine.
HEnvironmental note
When adding oil, take care not to spill any. If
oil enters the soil or waterways, it is harmful to
the environment.
!Only use engine oils and oil filters that have
been approved for vehicles with a service sys-
tem. You can obtain a list of the engine oils
and oil filters tested and approved in accord- ance with the Mercedes-Benz Specifications
for Service Products at any Mercedes-Benz
Service center.
Damage to the engine or exhaust system is
caused by the following:
Rusing engine oils and oil filters that have notbeen specifically approved for the service
system
Rreplacing engine oil and oil filters after the
interval for replacement specified by the
service system has been exceeded
Rusing engine oil additives.
!Do not add too much oil. adding too much
engine oil can result in damage to the engine
or to the catalytic converter. Have excess
engine oil siphoned off.
Example
XTurn cap :counter-clockwise and remove it.
XAdd engine oil.
If the oil level is at or below the MIN mark on
the oil dipstick, add 1.1 US qt (1.0 liter) of
engine oil.
XReplace cap :on the filler neck and tighten
clockwise.
Ensure that the cap locks into place securely.
XCheck the oil level again with the oil dipstick
(Ypage 353).
Further information on engine oil (
Ypage 429).
Additional service products
Checking coolant level
GWARNING
Certain components in the engine compart-
ment, such as the engine, radiator and parts
of the exhaust system, can become very hot.
Working in the engine compartment poses a
risk of injury.
Where possible, let the engine cool down and touch only the components described in the
following.
GWARNING
The cooling system is pressurized, particularly
when the motor is warm. If you open the cap,
you could be scalded if hot coolant sprays out.
There is a risk of injury.
Let the engine cool down before you open the
cap. Wear gloves and eye protection. Slowly
open the cap to relieve pressure.
356Engine compartment
Maintenance and care